Intramolecular condensation of nitro group with olefinic double bond

  • L. A. Simonyan
  • N. P. Gambaryan
  • P. V. Petrovskii
  • I. L. Knunyants
Organic and Biological Chemistry


A new reaction of nitro compounds was discovered on the example of the thermal isomerization of unsaturated nitrocarbinols and nitrodihydropyrans, consisting in the intramolecular addition of the nitro group to the olefinic double bond with the formation of the heterolytic 1,3,2-dioxazoline system.


Double Bond Nitro Group Nitro Compound Thermal Isomerization Olefinic Double Bond 
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Copyright information

© Consultants Bureau 1968

Authors and Affiliations

  • L. A. Simonyan
    • 1
  • N. P. Gambaryan
    • 1
  • P. V. Petrovskii
    • 1
  • I. L. Knunyants
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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