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The reaction of trichlorosilane with hydrocarbons at high temperatures

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A new reaction of trichlorosilane with saturated hydrocarbons has been found which takes place at about 600° in a circulating system and results in the formation of organic compounds of silicon of the type RSiCl3 with a yield of more than 60%.

  2. 2.

    Regardless of the nature of the hydrocarbon, methyltrichlorosilane and vinyltrichlorosilane are always found among the silico-organic compounds that are formed; their yield is as much as about 30% in some cases.

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Literature cited

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The recording and interpretation of the Raman and infrared spectra were carried out by L. A. Leites, to whom we express sincere thanks.

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Mironov, V.F., Maksimova, N.G. The reaction of trichlorosilane with hydrocarbons at high temperatures. Russ Chem Bull 11, 1223–1225 (1962). https://doi.org/10.1007/BF00908405

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  • DOI: https://doi.org/10.1007/BF00908405

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