Chemistry of polyenic and polyacetylenic compounds

Communication 7. Study of the hydration of ethylenic acetylenic alcohols
  • M. V. Mavrov
  • V. F. Kucherov
Organic and Biological Chemistry


  1. 1.

    The hydration of ethylenic acetylenic alcohols in presence of mercuric acetate in acetic acid is not accompanied by secondary isomerization processes and gives the corresponding unsaturated α-ketol acetic esters in high yields.

  2. 2.

    The pyrolysis of the acetic esters of 3-hydroxy-3,4-dimethyl-4-penten-2-one (II) and 3-hydroxy-4hexen-2-one (XIII) was studied, and the dienes (V) and (XIV) were obtained in satisfactory yields.



Alcohol Acetic Ester Hydration Acetic Acid 
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Copyright information

© Consultants Bureau Enterprises, Inc. 1963

Authors and Affiliations

  • M. V. Mavrov
    • 1
  • V. F. Kucherov
    • 1
  1. 1.N. D Zelinskii Institute of Organic ChemistryAcademy of SciencesUSSR

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