Chemistry of polyenic and polyacetylenic compounds

Communication 7. Study of the hydration of ethylenic acetylenic alcohols
  • M. V. Mavrov
  • V. F. Kucherov
Organic and Biological Chemistry
  • 19 Downloads

Summary

  1. 1.

    The hydration of ethylenic acetylenic alcohols in presence of mercuric acetate in acetic acid is not accompanied by secondary isomerization processes and gives the corresponding unsaturated α-ketol acetic esters in high yields.

     
  2. 2.

    The pyrolysis of the acetic esters of 3-hydroxy-3,4-dimethyl-4-penten-2-one (II) and 3-hydroxy-4hexen-2-one (XIII) was studied, and the dienes (V) and (XIV) were obtained in satisfactory yields.

     

Keywords

Alcohol Acetic Ester Hydration Acetic Acid 

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Copyright information

© Consultants Bureau Enterprises, Inc. 1963

Authors and Affiliations

  • M. V. Mavrov
    • 1
  • V. F. Kucherov
    • 1
  1. 1.N. D Zelinskii Institute of Organic ChemistryAcademy of SciencesUSSR

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