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Trans-1-vinyl-6-keto-9-methyl-Δ1 octaline in the reaction of the diene synthesis and some reactions of dl-18-nor-14-iso-3-hydroxy-Δ9(11)-androsten-15,17-dione acetate

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    We have studied the condensation of trans-1-vinyl-6-keto-9-methyl-Δ1-octaline (I) with methyl acrylate, nitropropylene, and methyl ester of trans-β-nitroa crylic acid.

  2. 2.

    We have carried out the synthesis of dl -18-nor-14-iso-Δ9(11)-epi-androsterone (VIII) and the mono-acetate of dl-18-nor-14-iso-3,17-dihydroxy-Δ9(11)-androsten-15-one (IX).

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Literature cited

  1. I. N. Nazarov and I. A. Gurvich, Izv. AN SSSR, Otd. khim. n.1959, 293.

  2. V. F. Kucherov and I. A. Gurvich, Izv. AN SSSR, Otd. khim. n.1961, 1152.

  3. V. F. Kucherov, I. M. Mil'shtein, and I. A. Gurvich, Zh. obshch. khimii31, 2832 (1961).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    B. F. Kucherov & I. A. Gurvich

Authors
  1. B. F. Kucherov
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  2. I. A. Gurvich
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Kucherov, B.F., Gurvich, I.A. Trans-1-vinyl-6-keto-9-methyl-Δ1 octaline in the reaction of the diene synthesis and some reactions of dl-18-nor-14-iso-3-hydroxy-Δ9(11)-androsten-15,17-dione acetate. Russ Chem Bull 11, 339–341 (1962). https://doi.org/10.1007/BF00908055

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  • DOI: https://doi.org/10.1007/BF00908055

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