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The reaction of hexafluoroacetone with olefins

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    We have carried out the reaction of hexafluoroacetone with olefins, resulting in the formation of bistrifluoromethyl-Δ2-alkenyl carbinols.

  2. 2.

    By the reaction of hexafluoroacetone with ethylene in the presence of aluminum chloride we have obtained bistrifluoromethyl-β-chloroethyl carbinol.

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Literature cited

  1. L. Bellamy, Infrared Spectra of Molecules [Russian translation] (Moscow, 1957) p. 44.

  2. D. C. England, J. Am. Chem. Soc.83, 224 (1961).

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Authors and Affiliations

  1. Institute of Organic Compounds of the Elements, Academy of Sciences of the USSR, USSR

    I. L. Knunyants & B. L. Lyatkin

Authors
  1. I. L. Knunyants
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  2. B. L. Lyatkin
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Knunyants, I.L., Lyatkin, B.L. The reaction of hexafluoroacetone with olefins. Russ Chem Bull 11, 329–331 (1962). https://doi.org/10.1007/BF00908049

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  • DOI: https://doi.org/10.1007/BF00908049

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