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Tautomerism and geometric isomerism in nitrogen derivatives of carbonyl compounds

6. Polarographic study of semi- and thiosemicarbazones of some aliphatic and alicyclic ketones

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study has been made of the polarographic behavior of semiand thiosemicarbazones of acetone, methyl ethyl ketone, methyl n-propyl'ketone, methyl isopropyl ketone, methyl n-butyl ketone, methyl n-amyl ke'tone, methyl n-hexyl ketone, diethyl ketone, cyclopentanone, cyclohexanone, and pinacoline semicarbazone.

  2. 2.

    It is proposed that the compounds investigated show a structure of ensemiand enthiosemicarbazine type in water-alcohol solutions.

  3. 3.

    The effect of alkyl groups on the ease of reduction of methyl alkyl ketone derivatives is explained from the point of view of present-day concepts in organic chemistry.

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Literature cited

  1. B. Gingras, R. Hornal, and C. Bayley, Canad. J. Chem.38, 712 (1960).

    Google Scholar 

  2. B. Gingras, R. Somorjai, and C. Bayley, Canad. J. Chem.39, 973 (1961).

    Google Scholar 

  3. P. W. Sadler, J. Chem. Soc.1961, 957.

  4. V. F. Toropova, Yu. P. Kitaev, and G. K. Budnikov, Zh. neorgan. khimii.6, 647 (1961).

    Google Scholar 

  5. Yu. P. Kitaev and G. K. Budnikov, Zavod. laboratoriya (in press).

  6. Chemistry and Medicine, Thiosemicarbazones (Collection of Papers Edited by G. N. Pershin) [in Russian] (Moscow, 1954).

  7. Yu. P. Kitaev, G. K. Budnikov, and A. E. Arbuzov, Izv. AN SSSR, Otd. khirn. n.1961, 824.

  8. Yu. P. Kitaev, G. K. Budnikov, and A. E. Arbuzov, Izv. AN SSSR, Otd. khim. n.1961, 1222.

  9. Yu. P. Kitaev, G. K. Budnikov, and A. E. Arbuzov, Izv. AN SSSR, Otd. khim. n.1961, 1772.

  10. V. Prelog and O. Hafliger, Helv. chim. acta32, 2088 (1949).

    Google Scholar 

  11. J. Young, J. Chem. Soc.1955, 1516.

  12. P. Zuman, Coll. Czechoslov. Chem. Commun.25, 3225 (1960).

    Google Scholar 

  13. R. Kalvoda, Coll. Czechoslov. Chem. Commun.25, 3071 (1960).

    Google Scholar 

  14. R. U. Taft, “Separating the effects of polar, spatil, and resonance factors on reactivity,” Collection: Spatial Effects in Organic Chemistry (edited by M. N'yumena) [Russian translation] (IL, 1960).

  15. P. Zuman, Coll. Czechoslov. Chem. Commun.15, 839 (1950).

    Google Scholar 

  16. Yu. P. Kitaev, G. K. Budnikov, T. V. Troepol'skaya, and A. E. Arbuzov, Dokl. AN SSSR137, 862 (1961).

    Google Scholar 

  17. Yu. P. Kitaev, G. K. Budnikov, and A. E. Arbuzov, Dokl. AN SSSR127, 818 (1959).

    Google Scholar 

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Authors and Affiliations

  1. A. E. Arbuzov Chemical Institute, Academy of Sciences of the USSR, Kazan

    Yu. P. Kitaev, G. K. Budnikov & I. M. Skrebkova

Authors
  1. Yu. P. Kitaev
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  2. G. K. Budnikov
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  3. I. M. Skrebkova
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Kitaev, Y.P., Budnikov, G.K. & Skrebkova, I.M. Tautomerism and geometric isomerism in nitrogen derivatives of carbonyl compounds. Russ Chem Bull 11, 224–230 (1962). https://doi.org/10.1007/BF00908021

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  • DOI: https://doi.org/10.1007/BF00908021

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