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Halogen substitution of a mercury atom bound with a saturated carbon atom

4. Reaction of benzylmercuric chloride with bromine in carbon tetrachloride
  • I. P. Beletskaya
  • O. A. Reutov
  • T. A. Azizyan
Inorganic and Analytical Chemistry
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Summary

  1. 1.

    A study had been made of the kinetics of the reaction of benzylmereuric chloride with bromine in carbon tetrachloride.

     
  2. 2.

    The reaction has first-order kinetics (first-order with respect to bromine, and zero order with respect to the mercuroorganic compound).

     
  3. 3.

    A study has been made of the effect of temperature on the reaction.

     
  4. 4.

    Adding compounds containing oxygen (ether, alcohols) changes the reaction mechanism. The reaction kinetics becomes second-order.

     
  5. 5.

    In their effect on the reaction rate, the additives may be arranged in the order: methanol > ethanol > ether > isopropyl alcohol > tertiary butyl alcohol.

     

Keywords

Alcohol Mercury Carbon Atom Isopropyl Alcohol Butyl Alcohol 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    I. P. Beletskaya, O. A. Reutov, and T. P. Gur'yanova, Izv. AN SSSR, Otd. khim. n.1961, 1589.Google Scholar
  2. 2.
    I. P. Beletskaya, O. A. Reutov, and T. P. Gur'yanova, Izv. AN SSSR, Otd. khim. n.1961, 1997.Google Scholar
  3. 3.
    I. P. Beletskaya, O. A. Reutov, and T. P. Gur'yanova, Izv. AN SSSR, Otd. khim. n.1961, 2278.Google Scholar
  4. 4.
    Organic Solvents [Russian translation] (IL, Moscow, 1958) p. 383.Google Scholar
  5. 5.
    J. Beuler, Chemistry of Coordination Compounds [Russian translation] (IL, Moscow, 1960).Google Scholar

Copyright information

© Consultants Bureau Enterprises, Inc. 1962

Authors and Affiliations

  • I. P. Beletskaya
    • 1
  • O. A. Reutov
    • 1
  • T. A. Azizyan
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityUSSR

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