Skip to main content
Log in

The separate determination of small amounts of ethylene oxide, formaldehyde, and acetaldehyde in mixed aqueous solutions

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    We have made a quantitative comparison of various reagents for determining ethylene oxide in dilute aqueous solutions according to the Deckert-Lubatti method.

  2. 2.

    KI+HI and Na2S2O3 can determine 97–100 and 76–78% ethylene oxide, respectively.

  3. 3.

    For mixed aqueous solutions of ethylene oxide, acetaldehyde, and formaldehyde we recommend the reagents: KI+HI (to determine ethylene oxide), hydroxylamine hydrochloride (sum of aldehydes) and Schiffs reagent (formaldehyde).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. Handbook of Chemistry and Physics, 37th Edition (1955) p. 924; A Short Handbook of Chemistry [in Russian] (GKhl, Moscow, 1954) p. 162.

  2. S. A. Elkhishen, J. Sci. Food Agr.1, 71 (1950); Chem. Abstrs. 44, 7187 (1950).

    Google Scholar 

  3. V. A. Pokrovskii, Zh. analit. khimii12, 273 (1957).

    Google Scholar 

  4. W. Decken, Z. analyt. chem.82, 297 (1930).

    Google Scholar 

  5. W. Decken, Angew. Chemie Ind.45, 559, 758 (1932).

    Google Scholar 

  6. W. Decken, Z. analyt. Chem.109, 166 (1937).

    Google Scholar 

  7. O. F. Lubatti, J. Soc. Chem. Ind.51, 361T (1932).

    Google Scholar 

  8. P. V. Zimakov, Ethylene Oxide [in Russian] (GKhl, Moscow-Leningrad, 1946).

    Google Scholar 

  9. P. V. Zimakov and V. A. Sokolova, Zavod. laboratoriya17, 1434 (1951).

    Google Scholar 

  10. J. H. Benedict, J. Am. Oil Chem. Soc.34, 450 (1957); Chem. Abstrs.51, 17201 (1957).

    Google Scholar 

  11. D. F. Walker, Formaldehyde [Russian translation] (GKhl, Moscow, 1957).

    Google Scholar 

  12. C. N. Satterfield, R. E. Wilson, R. M. LeClair, and R. C. Ried, Analyt. Chem.26, 1792 (1954).

    Google Scholar 

  13. C. E. Bricker and H. R. Johnson, Industr. and Engng. Chem. (Anal. Ed.)17, 400 (1945).

    Google Scholar 

  14. D. E. Kramm and C. L. Kolb, Analyt. Chem.27, 1076 (1955).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Samoilov, S.M., Andrievskii, V.N. & Kotlyarevskii, I.L. The separate determination of small amounts of ethylene oxide, formaldehyde, and acetaldehyde in mixed aqueous solutions. Russ Chem Bull 11, 184–190 (1962). https://doi.org/10.1007/BF00908015

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00908015

Keywords

Navigation