Effect of the methyl group on the isotope exchange rate for hydrogen in the o-, m-, and p-positions in tricarbonyltoluene chromium in alkaline media

  • D. N. Kursanov
  • V. N. Setkina
  • N. K. Baranetskaya
  • K. N. Anisimov
Brief Communications
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Conclusions

The hydrogen isotope exchange reaction of carbonyltoluene chromium in ethanol in the presence of a sodium alcoholate has been studied. The partial rate factors for the o-, m-, and p- positions in the aromatic ring in this system have been determined.

Keywords

Hydrogen Sodium Methyl Chromium Exchange Rate 

Literature cited

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    V. N. Setkina, N. K Baranetskaya, K. N. Anisimov, and D. N. Kursakov, Izv. Akad. Nauk SSSR, Ser. Khim., 1873 (1964).Google Scholar
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    A. Murray, and D. L. Williams, Organic Syntheses with Isotopes, Vol. 2, Interscience Publishers, New York, London (1958), p. 1448.Google Scholar
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    W. Strohmeier, Chem. Ber.,94, 2490 (1961); B. Nicholls, and M. C. Whiting, J. Chem. Soc., 551 (1959).Google Scholar

Copyright information

© Consultants Bureau 1969

Authors and Affiliations

  • D. N. Kursanov
    • 1
  • V. N. Setkina
    • 1
  • N. K. Baranetskaya
    • 1
  • K. N. Anisimov
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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