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Condensation of gem-dinitroalkanes with aliphatic aldehydes and amines

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

Gem-dinitroalkanes condense readily with acetaldehyde, propionaldehyde, butyraldehyde, and amines. The use of these aldehydes instead of formaldehyde extends the field of application of the Mannich reaction with nitro compounds.

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Literature cited

  1. P. Duden, K. Bock, H. Reid, Ber.38, 2036 (1905).

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  2. W. C. Johnson, R. D. Shennan, and R. A. Reid, Organic Reagents for Organic Analysis [Russian translation] (IL, Moscow, 1948), p. 56.

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Novikov, S.S., Fainzil'berg, A.A., Shvedova, S.N. et al. Condensation of gem-dinitroalkanes with aliphatic aldehydes and amines. Russ Chem Bull 9, 1908–1910 (1960). https://doi.org/10.1007/BF00907760

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  • DOI: https://doi.org/10.1007/BF00907760

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