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Successive elimination of the alcohol groups of 3,7-dimethyloctane-1,7-diol on a tricalcium phosphate catalyst

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The dehydration of 3,7-dimethyloctane-l,7-diol on a phosphate catalyst proceeds in stages: first to citronellol and then to 3,7-dimethyloctadiene.

  2. 2.

    The stepwise nature of the process is caused by the position of the hydroxyl groups (primary and tertiary) in the 3,7-dimethyloctane-l,7-diol molecule.

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Literature cited

  1. L. Kh. Friedlin and V. Z. Sharf, Kinetika i Kataliz,1, 247 (1960).

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  2. Z. Palfray, S. Sabetay, A. Rangel, Compt. rend.212, 911 (1941).

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  3. Dictionary of Organic Compounds [Russian translation] (IL, Moscow, 1949),1, pp. 934,558.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences USSR, USSR

    L. Kh. Freidlin & V. Z. Sharf

Authors
  1. L. Kh. Freidlin
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  2. V. Z. Sharf
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Freidlin, L.K., Sharf, V.Z. Successive elimination of the alcohol groups of 3,7-dimethyloctane-1,7-diol on a tricalcium phosphate catalyst. Russ Chem Bull 9, 1906–1907 (1960). https://doi.org/10.1007/BF00907759

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  • DOI: https://doi.org/10.1007/BF00907759

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