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Investigation of the effect of cho groups in the cellulose molecule on the stability of the acetal bond in an acid medium using model compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Comparison of the hydrolysis rates of D′-methoxy-D-hydroxy-methyldiglycolaldehyde and α-methylglucoside showed that a CHO group in the α-position relative to an acetal bond lowers the stability of the latter in an acid medium.

  2. 2.

    The formation of CHO groups at C2 and C3 in an oxidized unit of a cellulose molecule must lead to weakening of the acetal bond in it in an acid medium.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    Z. I. Kuznetsova & V. I. Ivanov

Authors
  1. Z. I. Kuznetsova
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  2. V. I. Ivanov
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Kuznetsova, Z.I., Ivanov, V.I. Investigation of the effect of cho groups in the cellulose molecule on the stability of the acetal bond in an acid medium using model compounds. Russ Chem Bull 9, 1894–1895 (1960). https://doi.org/10.1007/BF00907754

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  • DOI: https://doi.org/10.1007/BF00907754

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