Skip to main content
SpringerLink
Log in

A study in the field of the stereochemistry of cyclic compounds

Communication 35. Synthesis and configuration of the isomers of 7-methoxy-l,2,3,4,4a,9,10,10a-octahydrophenanthrene-1, 2-dicarboxylic acid with a cis-connection of cycles

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The synthesis of the four possible geometric isomers of 7-methoxy-l,2,3,4,4a,9,10,10a-octahydrophenanthrene-l, 2-dicarboxylic acid with a cis-connection of cycles has been achieved, and their configurations have been proved.

  2. 2.

    The possibility of conversion transformations of the cis-syn-cis-acid (III) has been established; this possibility explains the formation of two isomeric trans-acids (VI) and (V), and the cis-syn-cis-diester (XII).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. V. F. Kucherov, V. M. Andreev, and L. K. Lysanchuk, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk, No.10 (1960).

  2. I. N. Nazarov, V. F. Kucherov, and V. M. Andreev, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk, 715 (1956).

  3. V. M. Andreev, L. K. Lysanchuk, and V. F. Kucherov, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk, No.10 (1960).

  4. I. N. Nazarov and V. F. Kucherov, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk, 298 (1955).

  5. I. N. Nazarov, V. F. Kucherov, and V. M. Andreev, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk, 1091 (1956).

  6. V. F. Kucherov, V. M. Andreev, and I. N. Nazarov, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk, 1244 (1959).

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    V. F. Kucherov, L. K. Lysanchuk & V. M. Andreev

Authors
  1. V. F. Kucherov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. K. Lysanchuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. M. Andreev
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kucherov, V.F., Lysanchuk, L.K. & Andreev, V.M. A study in the field of the stereochemistry of cyclic compounds. Russ Chem Bull 9, 1860–1864 (1960). https://doi.org/10.1007/BF00907746

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00907746

Keywords

Search

Navigation