Relative reactivity of ω-trialkysilyl substituted alcohols and mercaptans with phenylisocyanates

  • V. F. Mironov
  • N. A. Pogonkina
Article
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Summary

  1. 1.

    In the homologous series of organosilicon alcohols of the type (CH3)3Si(CH2)nOH, the relative reactivity towards phenyl isocyanate is in the following ratio 2.5∶1∶1 for n=1∶2∶3.

     
  2. 2.

    In the analogous series of mercaptans (C2H5)2CH3Si(CH2)nSH the reactivity towards phenyl isocyanate has the order 1: 10: 10.

     

Keywords

Alcohol Phenyl Isocyanate Homologous Series Mercaptan 

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Copyright information

© Consultants Bureau 1961

Authors and Affiliations

  • V. F. Mironov
    • 1
  • N. A. Pogonkina
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryUSSR Academy of SciencesUSSR

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