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The decomposition of aryl diazonium borofluorides in nitrobenzene and ethyl benzoate in the presence of the free metal, copper powder

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

In the presence of copper powder the decomposition of aryl diazonium borofluorides in nitrobenzene and ethyl benzoate gives products of homolytic splitting of the diazonium salts. The synthesis of metalloorganic compounds from diazonium salts in the presence of metals occurs by a homolytic mechanism.

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Literature cited

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Authors and Affiliations

  1. Institute of Organic Compounds of the Elements, Academy of Sciences, USSR

    L. G. Makarova & M. K. Matveeva

Authors
  1. L. G. Makarova
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  2. M. K. Matveeva
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Makarova, L.G., Matveeva, M.K. The decomposition of aryl diazonium borofluorides in nitrobenzene and ethyl benzoate in the presence of the free metal, copper powder. Russ Chem Bull 9, 1838–1842 (1960). https://doi.org/10.1007/BF00907741

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  • DOI: https://doi.org/10.1007/BF00907741

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