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An investigation of systems containing concentrated hydrogen peroxide

Communication XXI. The ternary system Cu(OH)2-H2O2-H2O

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The system Cu(OH)2-H2O2-H2O has been studied by a solubility method at temperatures of -36°, -20°, 0° and 20°.

  2. 2.

    In addition to the peroxidic compound of copper formerly known, CuO2 · H2O, the existence of a new compound with a higher content of active oxygen, CuO2 · H2O2 · H2O has been established, this being formed at higher concentrations of hydrogen peroxide in the liquid phase.

  3. 3.

    A polythermal diagram constructed for the temperature range -36° to +20°, giving the limits of equilibrium existence of the solid phases ice, cupric hydroxide, CuO2 · H2O, and CuO2 · H2O2 · H2O, has been obtained.

  4. 4.

    The solid phases of peroxide type obtained have been submitted to additional thermal studies. The compound CuO2· H2O2 · H2O has served as a basis for the synthesis of anhydrous cupric peroxide, CuO2.

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Authors and Affiliations

  1. The N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences, USSR

    S. Z. Makarov, T. I. Arnol'd, N. N. Stasevich & E. V. Shorina

Authors
  1. S. Z. Makarov
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  2. T. I. Arnol'd
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  3. N. N. Stasevich
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  4. E. V. Shorina
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Makarov, S.Z., Arnol'd, T.I., Stasevich, N.N. et al. An investigation of systems containing concentrated hydrogen peroxide. Russ Chem Bull 9, 1789–1795 (1960). https://doi.org/10.1007/BF00907733

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  • DOI: https://doi.org/10.1007/BF00907733

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