Summary
The addition of HAl(i-C4H9)2 to dimethylfulvene proceeds in such a way that the hydrogen adds to the isopropyl group and the AlR2 to the carbon ring.
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Zakharkin, L.I., Gavrilenko, B.V., Parnes, Z.N. et al. Order of addition of diisobutylaluminum hydride to dimethylfulvene. Russ Chem Bull 9, 1413–1415 (1960). https://doi.org/10.1007/BF00907683
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DOI: https://doi.org/10.1007/BF00907683