Summary
The reaction of carbethoxymethylenetriphenylphosphorane with various aldehydes is a general method of synthesizing esters of α,β-unsaturated and polyenoic acids.
Literature cited
G. Wittig, W. Haag, Ber.88, 1654 (1955).
G. Wittig, U. Schollkopf, Chem. Ber.87, 1318 (1954).
O. Isler, H. Guttman, M. Montavon, R. Ruegg, G. Ryser, P. Zeller, Helv. chim. acta40, 1242 (1957).
O. Isler, W. Guex, R. Ruegg, G. Ryser, G. Saucy, U. Schwieter, M. Walter, A. Winterstein, Helv. chim, acta42, 864 (1959).
F. G. Fischer, K. Lowenberg, Liegigs Ann. Chem.494, 264 (1932).
Dictionary of Organic Compounds [Russian translation] (IL, Moscow, 1949).
A. Verley, Bull. Soc. chim. France (3)21, 417 (1899); L. Tetry, Bull. Soc. chim. France (3)27, 602 (1902).
E. P. Kohler, F. R. Rutler, J. Amer. Chem. Soc.48, 1036 (1926).
R. Kuhn, W. Hofer, Ber.63, 2164 (1930).
R. Kuhn, W. Badstubner, Ch. Grundmann, Ber.69, 98 (1936).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kucherov, V.F., Kovalev, B.G., Nazarova, I.I. et al. Use of Wittig reaction for synthesizing α,β-unsaturated and polyenoic acids. Russ Chem Bull 9, 1405–1407 (1960). https://doi.org/10.1007/BF00907680
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00907680