Summary
-
1.
By the hydrogenation of 3-methyl-1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1-penten-4-yn-3-ol and the Normant vinylation of β-ionone, 3-methyl-1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,4-pentadien-3-ol was prepared.
-
2.
Normant vinylation of the C18 3,4 dihydro ketone gave 3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexen1-yl)-1,6, 8-nonatrien-3-ol.
Similar content being viewed by others
Literature cited
I. N. Nazarov, L. A. Yanovskaya, B. P. Gusev, S. S. Yufit, V. I. Gunar, and V. A. Smit, Doklady Akad. Nauk SSSR114, 331 (1957).
I. N. Nazarov, L. A. Yanovskaya, B. P. Gusev, S. M. Makin, and I. I. Nazarova, Doklady Akad. Nauk SSSR114, 1029 (1957).
I. Heilbron, J. Chem. Soc., 868 (1946).
I. N. Nazarov and Zh. A. Krasnaya, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk, 870 (1958).
R. G. Gould and A. F. Thompson, J. Am. Chem. Soc.57, 340 (1935).
I. N. Nazarov, B. P. Gusev, and V. I. Gunar, Zhur. Obshchei Khim.28, 1444 (1958).
R. G. Gould, J. Biol. Chem.114, 41 (1936).
Author information
Authors and Affiliations
Additional information
The work was carried out under the supervision of I. N. Nazarov.
Rights and permissions
About this article
Cite this article
Yanovskaya, L.A. Possible methods of synthesizing substances allied to vitamin A. Russ Chem Bull 9, 1333–1337 (1960). https://doi.org/10.1007/BF00907665
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00907665