Summary
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1.
By the action of sodium dialkyl phosphites on 3-chlorocyclopentene, 2-cyclopenten-1-ylphosphonic esters were synthesized.
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2.
By the oxidation of the resulting esters with peroxyacetic acid the corresponding epoxides were prepared. Hydration of the esters gave trans-2,3-dihydroxycyclopentylphosphonic esters.
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L. Bellamy, Infrared Spectra of Molecules [Russian translation] (IL, Moscow, 1957) p. 130.
P. A. Akishin and V. M. Tatevskii, Vestnik Moskov. Univ.6, 2, Ser. Fiz.-Matemat, i Estestven. Nauk1, 103 (1951).
B. A. Arbuzov, Z. G. Isaeva, and E. G. Kataev, Uchen. Zapiski Kazansk. Univ.1, 175 (1950).
Organic Syntheses [Russian translation] (IL, Moscow, 1953) Vol. 4, p. 565.
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Arbuzov, B.A., Dianova (Ukhvatova), E.N. 2-Cyclopenten-1-ylphosphonic esters and some of their derivatives. Russ Chem Bull 9, 1301–1305 (1960). https://doi.org/10.1007/BF00907659
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DOI: https://doi.org/10.1007/BF00907659