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Action of sulfur, selenium, and sulfur chlorides on trialkylaluminums

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The action of sulfur, selenium, and sulfur chloride on trialkylaluminums was studied.

  2. 2.

    In the reaction of one g-atom of sulfur with one mole of trialkylaluminum the dialkyl (alkylthio) aluminum is formed; in the reaction of two and more gatoms of sulfur with one mole of trialkylaluminum the main reaction products are the corresponding disulfides, sulfides, and polysulfides; products of structure RAl (SR)2 and Al (SR)3 are not formed.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    L. I. Zakharkin & V. V. Gavrilenko

Authors
  1. L. I. Zakharkin
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  2. V. V. Gavrilenko
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Zakharkin, L.I., Gavrilenko, V.V. Action of sulfur, selenium, and sulfur chlorides on trialkylaluminums. Russ Chem Bull 9, 1294–1300 (1960). https://doi.org/10.1007/BF00907658

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  • DOI: https://doi.org/10.1007/BF00907658

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