Skip to main content
SpringerLink
Log in

Change in catalytic activity of nickel stearate during the oxidation of ethylbenzene

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    In the oxidation of ethylbenzene catalyzed by nickel stearate, the activity of the catalyst gradually falls as a result of reaction of nickel stearate with acids formed during, the oxidation.

  2. 2.

    The anomalous course of the kinetic curve of hydroperoxide accumulation during the catalyzed reaction is associated with deactivation of the catalyst.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. C. E. H. Bawn, Disc. Faraday Soc.14, 181 (1953).

    Google Scholar 

  2. E. T. Denisov and N. M. Emanuel', Zhur, Fiz. Khim.30, 2327 (1956).

    Google Scholar 

  3. V. K. Tsyskovskii, Production of Artificial Acids by Oxidation of Kerosene Fractions [in Russian] (Gostoptekhizdat, Moscow, 1954).

    Google Scholar 

  4. B. G. Freidin, Zhur. Prikladnoi Khim.30, 768 (1957).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    R. F. Vasil'ev, Z. G. Kozlova, L. G. Chuchukina, V. Ya. Shlyapintokh & N. M. Emanuel'

Authors
  1. R. F. Vasil'ev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Z. G. Kozlova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. G. Chuchukina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. Ya. Shlyapintokh
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. M. Emanuel'
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vasil'ev, R.F., Kozlova, Z.G., Chuchukina, L.G. et al. Change in catalytic activity of nickel stearate during the oxidation of ethylbenzene. Russ Chem Bull 9, 1244–1248 (1960). https://doi.org/10.1007/BF00907650

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00907650

Keywords

Search

Navigation