Electronic absorption spectra of certain palladium (II) bis-dioximates in organic solvents

  • I. P. Alimarin
  • A. A. Biryukov
  • T. I. Tikhvinskaya
  • V. I. Shlenskaya
Physical Chemistry


  1. 1.

    The electronic absorption spectra ofα-dimethylglyoxime, 1,2-cyclohexanedionedioxime, andα-furyldioxime in aqueous solutions at the pH of domination of the cis-HDforms were investigated with a resolution into Gaussian components.

  2. 2.

    The electronic absorption spectra of palladium (II) bis-dimethylglyoximate, bis-1,2-cyclohexane-dionedioximate, bis-1,2-cycloheptanedionedioximate, and bis-α-furyldioximate in benzene, chloroform, and ethanol solutions were investigated with a resolution into Gaussian components.

  3. 3.

    The electronic absorption spectra of the indicated internal complex compounds and the absorption spectra of the ligands were compared. The data obtained can be used for a comparison in calculations of the absorption spectra of these compounds by the molecular orbital method.



Aqueous Solution Benzene Chloroform Absorption Spectrum Palladium 
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Copyright information

© Consultants Bureau 1969

Authors and Affiliations

  • I. P. Alimarin
    • 1
  • A. A. Biryukov
    • 1
  • T. I. Tikhvinskaya
    • 1
  • V. I. Shlenskaya
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityUSSR

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