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Die stufenweise Synthese von 4,11,18,25-Tetra-tert-butyl-[1.1.1.1]metacyclophan-7,14,21,28-tetraol und 4,11-Dimethyl-[1.1.1.1]-metacyclophan-7,14,21,28-tetraol

Stepwise synthesis of 4,11,18,25-tetra-t-butyl-[1.1.1.1]metacyclophane-7,14,21,28-tetraol and 4,11-dimethyl-[1.1.1.1]metacyclophane-7,14,21,28-tetraol

  • Organische Chemie und Biochemie
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Abstract

Two phenolic alcohols with four phenolic units in their molecules are obtained by stepwise synthesis starting from simple phenolic derivatives. The phenolic alcohols are cyclized by boiling of a diluted solution in acetic acid. A third cyclic compound is obtained by debutylation of that cyclic compound which contains two neighbouringtert-butyl groups and two methyl groupspara to the phenolic hydroxyl groups.

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Authors and Affiliations

  1. Fachbereich Chemie, Universität Mainz, D-6500, Mainz, Bundesrepublik Deutschland

    Hermann Kämmerer, Günter Happel, Volker Böhmer & Dusanka Rathay

Authors
  1. Hermann Kämmerer
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  2. Günter Happel
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  3. Volker Böhmer
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  4. Dusanka Rathay
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Additional information

Meiner verehrten Kollegin, Frau Prof. Dr.Helga Wittmann, Universität Graz, gewidmet.

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Kämmerer, H., Happel, G., Böhmer, V. et al. Die stufenweise Synthese von 4,11,18,25-Tetra-tert-butyl-[1.1.1.1]metacyclophan-7,14,21,28-tetraol und 4,11-Dimethyl-[1.1.1.1]-metacyclophan-7,14,21,28-tetraol. Monatshefte für Chemie 109, 767–773 (1978). https://doi.org/10.1007/BF00907297

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  • DOI: https://doi.org/10.1007/BF00907297

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