Summary
The condensation of trifluoroethylene with paraformaldehyde in the presence of sulfuric and chlorosulfonic acids has been carried out. α-Fluorohydracrylic, α-fluoro-β-chloropropionic, and α-fluoro-β-bromopropionic acids have been obtained.
Literature cited
I. L. Knunyants, L. S. German, B. L. Dyatkin, and E. P. Mochaline, Zh. Vsesoyuznogo khimicheskogo obshchestva im. Mendeleeva,6, 114 (1961).
B. L. Dyatkin, E. P. Mochaline, and I. L. Knunyants, Dokl. AN SSSR,139, 106 (1961).
P. W. Kent, G. Hebblethwaite, and N. F. Taylor, J. Chem. Soc. 1960, 106.
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Knunyants, I.L., Dyatkin, B.L., German, L.S. et al. Condensation of formaldehyde with trifluoroethylene. Russ Chem Bull 11, 1589–1590 (1962). https://doi.org/10.1007/BF00907245
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DOI: https://doi.org/10.1007/BF00907245