Summary
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1.
Ethyleneaminocarbinol does not react with alcohols, and, in view of this, its production by the interaction of ethyleneimine with an alcoholic solution of formaldehyde has been developed.
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2.
Different types of reaction of ethyleneaminocarbinols with diazo compounds have been found: ethylene-aminocarbinol reacts in the carbonium form and α-(trichlorylmethyl)-ethylenearmnocarbinol reacts in the imonium form.
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3.
α-(Methyl)-ethyleneaminocarbinol takes part in the 1-ethyleneaminoalkylation of secondary amines.M
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Kostyanovskii, R.G., Yuzhakova, O.A. & Bistrov, V.F. Reactions of ethyleneaminocarbinols with diazo compounds. Russ Chem Bull 11, 1576–1579 (1962). https://doi.org/10.1007/BF00907240
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DOI: https://doi.org/10.1007/BF00907240