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Synthesis of polymers from aliphatic nitriles

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    As a result of the polyrecombination reaction some aliphatic nitriles (methyl cyanoacetate, malononitrile, adiponitrile) give polymers containing systems of conjugated bonds. In some cases the polymers have high softening points.

  2. 2.

    A possible scheme for the formation of these polymers is proposed that is in accord with the results of elementary analysis and of infrared and e.s.r. spectroscopy.

  3. 3.

    The electrophysical and thermomechanical properties of the polymers obtained were investigated.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    S. L. Sosin, V. V. Korshak, V. A. Vasnev & E. L. Baranov

Authors
  1. S. L. Sosin
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  2. V. V. Korshak
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  3. V. A. Vasnev
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  4. E. L. Baranov
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Additional information

The e.s.r. determinations were carried out at the Institute of Chemical Physics, Academy of Sciences, USSR, by N. M. Bazhin, to whom the authors express their thanks.

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Sosin, S.L., Korshak, V.V., Vasnev, V.A. et al. Synthesis of polymers from aliphatic nitriles. Russ Chem Bull 11, 1554–1559 (1962). https://doi.org/10.1007/BF00907234

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  • DOI: https://doi.org/10.1007/BF00907234

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