Summary
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1.
It was shown that organophosphorus polymers can be prepared with the aid of the polyrecombination reaction.
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2.
Poly[benzyldiphenylphosphine oxide] was prepared, and its properties were studied.
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3.
The presence of phosphorus in the monomer molecule has a passivating effect on the mobility of the hydrogen of the methylene group.
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4.
Some regularities in the polyrecombination process were examined.
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Korshak, V.V., Krongauz, E.S. & Gribkova, P.N. Preparation of a polymer from benzyldiphenylphosphine oxide by the polyrecombination reaction. Russ Chem Bull 11, 1549–1553 (1962). https://doi.org/10.1007/BF00907233
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DOI: https://doi.org/10.1007/BF00907233