Summary
-
1.
The configurations of cis- and trans-2-methyl-2-pentenoic acids were confirmed by physicochernical methods.
-
2.
Stereospecific syntheses of threo- and erythro-(±)-2,3-dihydroxy-2-methylvaleric acids are described, and their resolution into antipodes was effected.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
A. Lieben and S. Zeisel, Onatsch.4, 52 (1883).
A. A. Goldberg and R. P. Linstead, J. Chem. Soc. 1928, 2343.
J. Cason and M. J. Kalm, J. Organ. Chem.19, 1947 (1954).
C. Asselineau and J. Asselineau, Bull. Chim. France(1960)1776.
H. J. Lucas and A. N. Prater, J. Amer. Chem. Soc.59, 1682 (1937).
R. P. Linstead and G. J. May, J. Chem. Soc. 1927. 2565.
R. Adams and B. L. van Duuren, J. Amer. Chem. Soc.75, 4631 (1953).
S. Stallberg-Stenhagen, Arkiv Kemi6, 537 (1954).
D. H. Hey, J. Chem. Soc. 1928, 2321.
L. D. Bergel'son, É. V. Dyatlovitskaya, and V. V. Voronkova, Dokl. AN SSSR141, 84 (1961).
L. P. Kuhn, J. Amer. Chem. Soc.74, 2492 (1952).
M. M. Shemyakin, É. M. Bamdas, E. I. Vinogradova, D. P. Vitkovskii, M. A. Guberniev, V. N. Orekhovich, A. S. Khokhlov, Yu. B. Shvetsov, and L. A. Shchukina, Zh. obshch. khimii24, 2076 (1954).
Author information
Authors and Affiliations
Additional information
Member of the staff of the Institute of Organic Chemistry and Biochemistry of the Czechoslovakian Academy of Sciences.
Rights and permissions
About this article
Cite this article
Bergel'son, L.D., Dyatlovitskya, E.V., Tichy, M. et al. Unsaturated acids and macrocyclic lactones. Russ Chem Bull 11, 1525–1529 (1962). https://doi.org/10.1007/BF00907229
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00907229