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Heterofunctional cocondensation of acetoxymethyl-(phenyl)silanes with organosilicon compounds containing silicon-attached ethoxy groups

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    An investigation was made of the cocondensation of various organosilicon compounds containing silicon-attached ethoxy groups with acetoxymethyl(phenyl)silanes in presence of hydrochloric acid. The process leads to the formation of cocondensation products and ethyl acetate.

  2. 2.

    The following new organosilicon compounds were prepared by this reaction: 1,3-bischloromethyltetra-kistrimethylsiloxydisiloxane, 1,3-bischloromethyltetrakis(dirnethylphenylsiloxy)disiloxane, 1,3,5-trischloromethyl-pentakistrimethylsiloxytrisiloxane, 1-[(methacryloyloxy)methyl]tetrarnethyl-3-phenyldisiloxane, 1-[(methacryloyl-oxy)methyl[trirnethyl-3,3-diphenyldisiloxane, 1-[(methacryloyloxy)methyl-dimethyl-3,3,3-triphenyldisiloxane, and 3-[(methacryloyloxy)methyl]pentamethyl-1,5-diphenyltrisiloxane.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    K. A. Andrianov, A. K. Dabagova & Zh. S. Syrtsova

Authors
  1. K. A. Andrianov
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  2. A. K. Dabagova
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  3. Zh. S. Syrtsova
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Andrianov, K.A., Dabagova, A.K. & Syrtsova, Z.S. Heterofunctional cocondensation of acetoxymethyl-(phenyl)silanes with organosilicon compounds containing silicon-attached ethoxy groups. Russ Chem Bull 11, 1487–1491 (1962). https://doi.org/10.1007/BF00907221

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  • DOI: https://doi.org/10.1007/BF00907221

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