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Determination of the reversible potential of the nickel electrode at high temperatures

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    True equilibrium is established in the Ni-Ni++ system at high temperatures and the reversible potential of the nickel electrode can then be obtained.

  2. 2.

    Using the experimental data, the normal potential of nickel at 25° proved to be equal to -0.270 ± 0.005 V relative to the standard hydrogen electrode.

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Literature cited

  1. W. M. Latimer, The Oxidation States of the Elements and Their Potentials in Aqueous Solutions [Russian translation], IL, Moscow (1954); Lewis and Randall, Chemical Thermodynamics [Russian translation], ONTI, Leningrad (1936).

    Google Scholar 

  2. M. M. Haring and G. V. Bosch, J. Phys. Chem.33, 161 (1929); N. M. Deshalyt, P. S. Vasil'ev, and A. I. Rabinovich, Zh. fiz. khimii,5, 534 (1934).

    Google Scholar 

  3. A. T. Vagramyan and Yu. S. Petrova, The Physicomechanical Properties of Electrolytic Deposits of Metals [in Russian], Izd. AN SSSR, Moscow (1960).

    Google Scholar 

  4. A. J. Bethune de, T. S. Licht, and N. Swendeman, J. Electrochem. Soc.106, 616 (1959).

    Google Scholar 

  5. L. Sauer, Z. phys. Chem.47, 146 (1904); R. Luther and A. C. Michin, Z. Elektrochem.14, II 828 (1908); F. Foerster, Elektrochemie wässerigen Lösungen, Leipzig (1922).

    Google Scholar 

  6. H. Harned and B. Owen, The physical chemistry of electrolit solution, 3-ed., N.Y. (1958).

  7. R. W. Money and C. W. Davies, Trans. Faraday Soc.28, 609 (1932).

    Google Scholar 

  8. V. P. Kondrat'ev and S. V. Gorbachev, Zh. fiz. khimii,35, 671 (1961).

    Google Scholar 

  9. M. H. Lietzke and R. W. Stoughton, J. Amer. Chem. Soc.75, 5226 (1953).

    Google Scholar 

  10. A. N. Frumkin, V. S. Bagotskii, Z. A. Iofa and, and B. N. Kabanov, The Kinetics of Electrode Processes [in Russian], Izd. MGU (1952); V. N. Kuznetsova, A. P. Popkov, L. A. Uvarov, and A. T. Vagramyan, Zh. fiz. khimii,35, 1406 (1961).

  11. N. N. Kavtaradze, Zh. fiz. khimii,32, 909, 1214 (1958).

    Google Scholar 

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Authors and Affiliations

  1. The Institute of Physical Chemistry, Acad. Sci., USSR

    A. T. Vagramyan & L. A. Uvarov

Authors
  1. A. T. Vagramyan
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  2. L. A. Uvarov
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Vagramyan, A.T., Uvarov, L.A. Determination of the reversible potential of the nickel electrode at high temperatures. Russ Chem Bull 11, 1438–1440 (1962). https://doi.org/10.1007/BF00907212

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  • DOI: https://doi.org/10.1007/BF00907212

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