Conclusions
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1.
In the interaction of dialkylphosphites with diacetone alcohol in presence of catalytic amounts of sodium alcoholates, 2-alkoxy-2-oxo-3,5,5-trimethyl-1,2-oxaphospholanols-3 were obtained.
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2.
A scheme of their formation was proposed.
Literature cited
N. I. Rizpolozhenskii, Some Problems of Organic Chemistry [in Russian], Izd. Kazanskogo Univ., Kazan' (1964).
V. S. Abramov, Dokl. AN SSSR,73, 487 (1950).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 210–212, January, 1967.
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Rizpolozhenskii, N.I., Mukhametov, F.S. Interaction of dialkylphosphites with diacetone alcohol. Russ Chem Bull 16, 208–210 (1967). https://doi.org/10.1007/BF00907138
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DOI: https://doi.org/10.1007/BF00907138