Conclusions
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1.
The action of mercuric oxide on fluorodinitromethane gives bis(fluorodinitromethyl)mercury, which is readily halogenated to give fluorochloro-, fluorobromo-, and fluoroiododinitromethane.
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2.
For the example of the reaction between N-(α-chloromethyl)-benzamide and bis(fluorodinitromethyl) mercury it was shown that the latter can act as a fluorodinitromethylating agent.
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Literature cited
S. S. Novikov, T. I. Godovikova, and V. A. Tartakovskii, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 505 (1960).
V. I. Slovetskii, V. A. Tartakovskii, and S. S. Novikov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1400 (1962).
L. V. Okhlobystina, G. Ya. Legin, and A. A. Fainzil'berg, Dokl. Akad. Nauk SSSR,176, 1086 (1967).
L. V. Okhlobystina, V. M. Khutoretskii, and A. A. Fainzil'berg, Izv. Akad. Nauk SSSR, Ser. Khim., 482 (1969).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 708–709, March, 1969.
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Okhlobystina, L.V., Legin, G.Y. & Fainzil'berg, A.A. Preparation and some reactions of bis(fluorodinitromethyl)mercury. Russ Chem Bull 18, 641–643 (1969). https://doi.org/10.1007/BF00906998
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DOI: https://doi.org/10.1007/BF00906998