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Reaction of copper acetylides with tetracyanoquinodimethane and tetracyanoethylene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Tetracyanoquinodimethane (TCQ) reacts with copper phenylacetylide to form a complex of copper with TCQ and diphenylbutadiyne.

  2. 2.

    The reaction between copper phenylacetylide and tetracyanoethylene (TCE) leads to the replacement of one of the nitrile groups in TCE by a phenylethinyl group.

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Literature cited

  1. R. Vinkler, Usp. Khim.,32, 1525 (1963).

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  2. B. L. Melby, R. J. Harder, W. R. Hertler, R. E. Benson, and W. E. Mochel, J. Amer. Chem. Soc.,84, 3374 (1962).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    L. Yu. Ukhin, A. M. Sladkov & Zh. I. Orlova

Authors
  1. L. Yu. Ukhin
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  2. A. M. Sladkov
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  3. Zh. I. Orlova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 705–706, March, 1969.

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Ukhin, L.Y., Sladkov, A.M. & Orlova, Z.I. Reaction of copper acetylides with tetracyanoquinodimethane and tetracyanoethylene. Russ Chem Bull 18, 637–638 (1969). https://doi.org/10.1007/BF00906996

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  • DOI: https://doi.org/10.1007/BF00906996

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