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Stereochemistry of the reduction of 1, 5-dimethylpiperidone-3

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The stereochemistry of the hydride and catalytic reduction of 1, 5-dimethylpiperidone-3 is studied.

  2. 2.

    The results obtained are associated with the specific adsorption of the 3-ketopiperidine molecule on the catalyst surface or with the structure of the ionic pair NΘ... BH4Θ in the hydride reduction in aqueous solution.

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Literature cited

  1. É. A. Mistryukov, Izv. Akad. Nauk SSSR, Ser. Khim., 1832 (1965).

  2. É. A. Mistryukov, Izv. Akad. Nauk SSSR, Ser. Khim., 1826 (1965).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    É. A. Mistryukov & G. T. Katvalyan

Authors
  1. É. A. Mistryukov
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  2. G. T. Katvalyan
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 702–705, March, 1969.

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Mistryukov, É.A., Katvalyan, G.T. Stereochemistry of the reduction of 1, 5-dimethylpiperidone-3. Russ Chem Bull 18, 634–636 (1969). https://doi.org/10.1007/BF00906995

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  • DOI: https://doi.org/10.1007/BF00906995

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