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The problem of equilibrium adsorption dynamics for a rectangular isotherm

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The problem of equilibrium adsorption dynamics with the calculation of longitudinal diffusion has been studied for the limiting case of a rectangular isotherm.

  2. 2.

    An approximate solution to this problem for constant flux velocity, which permits us to correctly estimate the time of onset of the parallel-transport region, has been obtained.

  3. 3.

    An exact solution to the same problem for the case when the flux velocity is inversely proportional to the square root of the time has been found.

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Literature cited

  1. V. V. Rachinskii, Introduction to the General Theory of Sorption Dynamics and Chromatography [in Russian], Nauka (1964).

  2. V. F. Frolov and P. G. Romankov, Teor. Osnovy Khim. Teknol.,2, 396 (1968).

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Authors and Affiliations

  1. Institute of Physical Chemistry, Academy of Sciences of the USSR, USSR

    P. P. Zolotarev

Authors
  1. P. P. Zolotarev
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3 pp. 700–702, March, 1969.

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Zolotarev, P.P. The problem of equilibrium adsorption dynamics for a rectangular isotherm. Russ Chem Bull 18, 631–633 (1969). https://doi.org/10.1007/BF00906994

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  • DOI: https://doi.org/10.1007/BF00906994

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