Conclusions
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1.
The composition of the primary decomposition products of guanidine perchlorate at 500~ and 10 -5 mm Hg pressure has been studied with the aid of a time-of-flight mass spectrometer.
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2.
Only one third of the guanidine perchlorate decomposes in vacuo according to the previously assumed reaction into ammonia, perchloric acid and cyanamide, and two thirds decomposes by a dissociation reaction into perchloric acid and CH5N3.
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Literature cited
A. Glasner and A. Makovki, J. Chem. Soc., 182 (1953).
A. Glasner and A. Makovki, Bull. Research Council Israel,3, 89 (1953).
A. Glasner and A. Makovki, J. Chem. Soc., 1606 (1954).
O. P. Korobeinichev, V. V. Boldyrev, and Yu. Ya. Karpenko, Fizika Goreniya i Vzryva,1, 33 (1968).
V. V. Boldyrev, O. P. Korobeinichev, and Yu. Ya. Karpenko, Izv. Akad. Nauk SSSR, Seriya Khim., 1372 (1968).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 696–697, March, 1969.
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Boldyrev, V.V., Korobeinichev, O.P. Mass-spectrometric study of the primary stages in the decomposition of guanidine perchlorate. Russ Chem Bull 18, 625–626 (1969). https://doi.org/10.1007/BF00906991
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DOI: https://doi.org/10.1007/BF00906991