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Oxidative combination of aromatic compounds in systems containing ruthenium complexes

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A small yield of diphenyl is obtained in the presence of ruthenium hydroxychloride and oxalic acid in 50% ethyl alcohol.

  2. 2.

    The ruthenium hydroxychloride -sodium acetate system in acetic acid is an agent for oxidative combination of phenols.

  3. 3.

    In the presence of ruthenium hydroxychloride as catalyst hydrogen peroxide oxidizes 2,4,6-triterbutylphenol to 2,6-diterbutyl-1,4-benzoquinone and 4-hydroxy-2,4,6-triterbutyl-2,5-cyclohexadiene-1-one and oxidizes phenols (V) and (VI) to products of oxidative combination.

  4. 4.

    In the presence of palladium chloride and sodium acetate in an atmosphere of oxygen (or argon) only the products of oxidative combination of phenols (III) and V are obtained.

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Literature cited

  1. J. R. Lewis, Chem. and Ind., 1672 (1964); 159 (1962).

  2. P. Kovacik, J. Organ. Chem.29, 100 (1964).

    Google Scholar 

  3. R. van Helden and G. Verberg, Recueil Trav. Chim.,84, 263 (1965).

    Google Scholar 

  4. J. Chatt and J. M. Davidson, J. Chem. Soc., 843 (1965).

  5. J. A. Connor and E. A. V. Ebsworth, Adv. Inorgan. Chem. Radiochem.,6, 279 (1964).

    Google Scholar 

  6. K. Kahr, Agnew. Chemie,72, 135 (1960); K. Kahr. Chem. Ber.,93, 132 (1960).

    Google Scholar 

  7. L. V. Gorbunova, N. S. Vasileiskaya, G. A. Razuvaev, and M. L. Khidekel', Zh. Organ. Khim.,2, 1233 (1966).

    Google Scholar 

  8. V. V. Karpov, M. L. Khidekel', L. V. Gorbunova, and G. A. Razuvaev, Izv. Akad. Nauk SSSR, Ser. Khim, 1717 (1965).

  9. J. Horner and S. Gôwecke, Chem. Ber,94, 1291 (1961).

    Google Scholar 

  10. W. Flaig and J. Ch. Saalfeld, Liebigs Ann. Chem.,626, 215 (1959).

    Google Scholar 

  11. K. Auwers and Th. V. Markovits, Chem. Ber.,38, 226 (1905).

    Google Scholar 

  12. H. M. Dort, Recueil Trav. Chim.,86, 520 (1967).

    Google Scholar 

  13. E. Müller and K. Ley, Chem. Ber.,88, 601 (1955).

    Google Scholar 

  14. Y. Ogata and T. Morimoto, Tetrahedron,21, 2791 (1965).

    Google Scholar 

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Authors and Affiliations

  1. Branch of the Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    N. F. Gol'dshleger & M. L. Khidekel'

Authors
  1. N. F. Gol'dshleger
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  2. M. L. Khidekel'
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 675–679, March, 1969.

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Gol'dshleger, N.F., Khidekel', M.L. Oxidative combination of aromatic compounds in systems containing ruthenium complexes. Russ Chem Bull 18, 605–608 (1969). https://doi.org/10.1007/BF00906985

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  • DOI: https://doi.org/10.1007/BF00906985

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