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Oxidation of cyclohexane in solutions of tertiary butanol

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The rate constants of chain propagation and termination in the oxidation of cyclohexane in tertbutanol were measured.

  2. 2.

    The solvation of cyclohexyl peroxide radicals by tert-butanol substantially lowers their reactivity in the oxidation reaction.

  3. 3.

    The contribution of nonspecific solvation (on account of the polarity of the medium) and specific solvation (on account of the formation of hydrogen bonds between the hydrogen atoms of solvent molecules and the unpaired electron of the peroxide radical) to reactions of chain propagation and termination was calculated.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemical physics, Academy of Sciences of the USSR, USSR

    G. E. Zaikov & Z. K. Maizus

Authors
  1. G. E. Zaikov
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  2. Z. K. Maizus
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.3, pp.598–603, March, 1969.

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Zaikov, G.E., Maizus, Z.K. Oxidation of cyclohexane in solutions of tertiary butanol. Russ Chem Bull 18, 534–538 (1969). https://doi.org/10.1007/BF00906972

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  • DOI: https://doi.org/10.1007/BF00906972

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