Conclusions
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1.
Dipole moments and molar Kerr coefficients of a number of substituted bicyclo[2, 2, 2]octenes and their epoxy derivatives were measured.
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2.
The axes of the ellipsoids of polarizability of the carbon-carbon double bond, the oxide and five-membered anhydride rings were calculated.
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3.
In the oxidation of bicyclooctenes possessing an endo-oriented methyl group or anhydride ring, exo-oxides are formed, while in the oxidation of endo-cyano-derivatives a mixture of exo- and endo-oxides in a 4∶1 ratio is formed.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 548–555, March, 1969.
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Arbuzov, B.A., Grozina, L.A. & Vereshchagin, A.N. Dipole moments, molar Kerr coefficients, and structures of certain substituted bicyclo[2, 2, 2] octenes and their epoxy derivatives. Russ Chem Bull 18, 489–494 (1969). https://doi.org/10.1007/BF00906963
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DOI: https://doi.org/10.1007/BF00906963