Skip to main content
SpringerLink
Log in

Study of reactions of protonation and decomposition of anion radicals of certain nitro-compounds by the EPR method

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The protonation of anion radicals of nitrobenzene and α-nitronaphthalene was investigated. The reaction proceeds at a very high rate, close to the rate of diffusion, and has a practically zero activation energy.

  2. 2.

    The decomposition of the anion radical of nitro-tert-butane has an activation energy of 18.3 kcal /mole.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. K. A. Bilevich, N. N. Bubnov, V. V. Bukhtiyarov, and O. Yu. Okhlobystin, Dokl. Akad. Nauk SSSR,174, 594 (1967).

    Google Scholar 

  2. S. M. Shein, L. V. Brynkhevetskaya, V. N. Panfilov, N. M. Bazhin, and V. V. Voevodsky, International Symposium on Free Radicals, 8th, Summaries Papers, Novosibirsk (1967), p. 165.

  3. A. J. Birsh and H. Smith, Quart. Rev.,12, 17 (1958).

    Google Scholar 

  4. L. J. Michaelis, Biol. Chem.,96, 703 (1932).

    Google Scholar 

  5. R. Pointeau, J. Favede, P. Delhaes, J. Chim. Phys. et Phys.-Chim. Biol.,61, 1129 (1964).

    Google Scholar 

  6. E. Janzen and J. Gerlock, Organ. Met. Chem.,8, 354 (1967).

    Google Scholar 

  7. N. I. Terekhova, É. S. Petrov, and A. M. Shatenshtein, Reakts. Sposobnost' Organ. Soed.,4, 638 (1967).

    Google Scholar 

  8. Ya. P. Stradyn', Polarography of Organic Nitro-Compounds [in Russian], Izd-vo AN LatvSSR, Riga (1961).

    Google Scholar 

  9. A. H. Maki and D. H. Geskie, J. Chem. Phys.,33, 825 (1960).

    Google Scholar 

  10. L. H. Piette, P. Ludwig, and R. N. Adams, J. Amer. Chem. Soc.,84, 4212 (1962).

    Google Scholar 

  11. A. K. Hoffman, W. G. Hodgson, D. L. Maricle, and W. H. Jura, J. Amer. Chem. Soc.,86, 631 (1964).

    Google Scholar 

  12. V. I. Vedeneev, L. V. Gurvich, V. N. Kondrat'ev, V. A. Medvedev, and E. L. Frankevich, Cleavage Energy of Chemical Bonds. Ionization Potentials and Electron Affinity [in Russian], Izd-vo AN SSSR, Moscow (1962).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    A. I. Prokof'ev & S. P. Solodovnikov

Authors
  1. A. I. Prokof'ev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. P. Solodovnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 544–548, March, 1969.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Prokof'ev, A.I., Solodovnikov, S.P. Study of reactions of protonation and decomposition of anion radicals of certain nitro-compounds by the EPR method. Russ Chem Bull 18, 485–488 (1969). https://doi.org/10.1007/BF00906962

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00906962

Keywords

Search

Navigation