Monatshefte für Chemie / Chemical Monthly

, Volume 107, Issue 2, pp 433–437 | Cite as

Ramanspektroskopische Untersuchungen an festem Vanadiumoxidtrichlorid VOCl3

  • A. Feza Demiray
  • Wolfgang Brockner
Anorganische, Struktur- und Physikalische Chemie

Raman spectrum of solid VOCl3

Abstract

A high resolution Raman spectrum of polycrystalline VOCl3 at −196 °C has been recorded. Besides the chlorine isotope splitting a further splitting of 3 of the 6 fundamentals has been observed. The number of the Raman lines in the ν4 and ν6 region and the intensity ratios in the ν2 region will be explained by a factor group splitting of 2 VOCl3 molecules in the unit cell.

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Literatur

  1. 1.
    E. B. Wilson, J. C. Decius undP. C. Cross, Molecular Vibrations. New York: McGraw-Hill. 1955.Google Scholar
  2. 2.
    H. J. Eichhoff undF. Weigel, Z. Anorg. Allg. Chem.275, 267 (1954).Google Scholar
  3. 3.
    F. A. Miller undL. R. Cousins, J. Chem. Phys.26, 329 (1957).Google Scholar
  4. 4.
    I. R. Beattie, K. M. S. Livingston, D. J. Reynolds undG. A. Ozin, J. Chem. Soc.A 1970, 1210.Google Scholar
  5. 5.
    G. A. Ozin, Prog. Inorg. Chem.14, 173 (1971).Google Scholar
  6. 6.
    R. J. H. Clark undP. D. Mitchell, J. Chem. Soc. Dalton1972, 2429.Google Scholar
  7. 7.
    H. Hovdan, S. J. Cyvin undW. Brockner, Z. Naturforsch.29 a, 706 (1974).Google Scholar
  8. 8.
    W. Bues, W. Brockner undF. Demiray, Spectrochim. Acta30 A, 579 (1974).Google Scholar
  9. 9.
    W. Brockner, H. Hovdan undS. J. Cyvin, Z. Naturforsch.29 a, 620 (1974).Google Scholar
  10. 10.
    W. Brockner undH. Hovdan, Mh. Chem.105, 750 (1974).Google Scholar
  11. 11.
    L. Kolditz, Anorganikum, S. 703. Berlin: VEB Deutscher Verlag der Wissenschaften. 1967.Google Scholar
  12. 12.
    W. Bues, W. Brockner undD. Grünewald, Spectrochim. Acta28 A, 1519 (1972).Google Scholar
  13. 13.
    K. Olie, Dissertation, Universität Amsterdam, 1974.Google Scholar

Copyright information

© Springer-Verlag 1976

Authors and Affiliations

  • A. Feza Demiray
    • 1
  • Wolfgang Brockner
    • 1
  1. 1.Anorganisch-Chemisches InstitutTechnische Universität ClausthalClausthal-ZellerfeldBundesrepublik Deutschland

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