Monatshefte für Chemie / Chemical Monthly

, Volume 107, Issue 2, pp 395–400 | Cite as

Komplexe des zweiwertigen Molybdäns; Derivate des Oktahalodimolybdat(II)-Ions, 3. Mitt.: Darstellung und Charakterisierung von Jodokomplexen

  • J. V. Brenčič
  • D. Dobčnik
  • P. Šegedin
Anorganische, Struktur- und Physikalische Chemie

Coordination compounds of molybdenum(II), derivatives of the octahalodimolybdate(II) ion, III. Synthesis and characterization of iodo complexes


(picH)2Mo2I6(H2O)2 was prepared from (picH)2Mo2Br6(H2O)2 in HI solutions (picH=4-methylpyridineum cation). This compound reacts with pyridine and 4-methylpyridine at 80°C giving Mo2I4L4. Both products are starting materials for the preparation of Mo2I4(NH3)4 and Mo2I4bipy2 (bipy=2,2′-bipyridine). Room temperature magnetic measurements, IR spectra, X-ray diffraction, chemical evidence and thermogravimetric analysis in part were used for the identification of the new compounds.


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Copyright information

© Springer-Verlag 1976

Authors and Affiliations

  • J. V. Brenčič
    • 1
  • D. Dobčnik
    • 1
  • P. Šegedin
    • 1
  1. 1.Laboratorium für anorganische ChemieUniversität LjubljanaLjubljanaJugoslawien

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