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Schiff base complexes of dioxouranium(VI). VII. Dioxouranium(VI) acetate complexes with monobasic bidentate and bibasic tridentateSchiff bases

UO2 2+-Komplexe von Schiff-Basen. VII. Uranylacetat-Komplexe mit monobasischen zweizähnigen und bibasischen dreizähnigen Schiff-Basen

  • Anorganische, Struktur- und Physikalische Chemie
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Abstract

1∶1 and 1∶2 molar reactions of dioxouranium(VI) acetate dihydrate with the monobasic bidentateSchiff bases,o-HOC6H4CH=NR oro-HOC10H6CH=NR (R=C2H5,n-C3H7,n-C4H9 or C6H5) and bibasic tridentateSchiff bases,o-HOC6H4CH=NR(OH) oro-HOC10H6CH=NR(OH) (R=−CH2CH(CH3)- or —CH2CH2CH2−) have been studied and derivates of the type UO2(OAc)2(SBH), UO2(OAc)2(SBH)2, UO2(OAc)2(SBH 2) and UO2(OAc)2(SBH 2)2 (whereSBH andSBH 2 represent monobasic bidentate and bibasic tridentateSchiff base molecules respectively) have been isolated. These have been characterized by elemental analysis, conductance measurements and IR spectral studies.

Zusammenfassung

Es wurden in 1:1- und 1:2-molaren Reaktionen von UO2(OAc)2·2H2O mitSchiff-Basen (L) Komplexe des Typs UO2(OAc)2 L bzw. UO2(OAc)2 L 2 isoliert. Die Komplexe wurden mittels Elementaranalyse, Leitfähigkeitsmessungen und IR-Spektren untersucht.

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Authors and Affiliations

  1. Chemical Laboratories, University of Rajasthan, Jaipur, India

    Ram G. Vijay & Jagdish P. Tandon

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  1. Ram G. Vijay
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  2. Jagdish P. Tandon
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Vijay, R.G., Tandon, J.P. Schiff base complexes of dioxouranium(VI). VII. Dioxouranium(VI) acetate complexes with monobasic bidentate and bibasic tridentateSchiff bases. Monatshefte für Chemie 110, 899–906 (1979). https://doi.org/10.1007/BF00906686

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