Influence of nitrobenzene on the reactivity of certain aroxyl radicals in the reaction with di-tert-butyl peroxide and on the EPR spectra of these radicals
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The reactivity of certain aroxyl radicals was studied in the reaction with di-tert-butyi peroxide in the present of nitrobenzene.
These radicals form π-complexes with nitrobenzene.
A change in the HFI constants was detected in the EPR spectrum of radical (III) depending on the nitrobenzene concentration. This change was described on the assumption of a stepwise double complex formation of the radical with nitrobenzene.
KeywordsPeroxide Complex Formation Nitrobenzene Double Complex Nitrobenzene Concentration
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