Monatshefte für Chemie - Chemical Monthly

, Volume 106, Issue 5, pp 1071–1079 | Cite as

Neue rhodanilatähnliche Verbindungen mit Morpholin

  • Ion Gănescu
  • Csaba Várhelyi
  • Gheorghe Brînzan
  • Liviu Boboc
Anorǵanische, Struktur- und physikalische Chemie

New rhodanilate like compounds with morpholine

Abstract

Substitution reactions of K3[Cr(NCS)6] with morpholine were studied. The formula of the complex anion, [Cr(NCS)4(morph)2], was established.23 new complex compounds of these types have been prepared from the hydrochlorides of some aliphatic or heterocyclic amines, alkaloids and cobalt(III)ammine bases resp.

Their thermal behaviour and the mechanism of pyrolysis of these salts was studied by derivatographic methodes. From UV and IR spectra some structural problems are resolved and discussed.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literatur

  1. 1.
    J. Roessler, Ann. Chem.141, 189 (1867).Google Scholar
  2. 2.
    R. Ripan, I. Gănescu undCs. Várhelyi, Rev. Roumaine Chim.11, 473 (1966).Google Scholar
  3. 3.
    R. Ripan, Cs. Várhelyi undI. Gănescu, Rev. Roumaine Chim.11, 717 (1966).Google Scholar
  4. 4.
    R. Ripan, I. Gănescu undCs. Várhelyi, Rev. Roumaine Chim.11, 1051 (1966).Google Scholar
  5. 5.
    R. Ripan, Cs. Várhelyi undI. Gănescu, Rev. Roumaine Chim.11, 1057 (1966).Google Scholar
  6. 6.
    P. Pfeiffer, Ber. dtsch. chem. Ges.34, 4303 (1901).CrossRefGoogle Scholar
  7. 7.
    P. Pfeiffer undB. Werdelmann, Z. anorg. Chem.263, 31 (1950).CrossRefGoogle Scholar
  8. 8.
    M. Bergmann, J. Biol. Chem.110, 465 (1935).Google Scholar
  9. 9.
    Cs. Várhelyi undI. Gănescu, Mh. Chem.98, 472 (1967).Google Scholar
  10. 10.
    R. Ripan, I. Gănescu undCs. Várhelyi, Z. anorg. Chem.357, 140 (1968).CrossRefGoogle Scholar
  11. 11.
    J. Meisenheimer undE. Kinderlen, Ann. Chem.438, 217 (1924).CrossRefGoogle Scholar
  12. 12.
    I. Gănescu, D. Oprescu undCs. Várhelyi, Mh. Chem.105, 525 (1974).Google Scholar
  13. 13.
    I. Gănescu, A. Popescu undM. Cioică, Chem. Analit. [Warszawa]17, 1169 (1972).Google Scholar
  14. 14.
    I. Gănescu, D. Oprescu, A. Popescu undCs. Várhelyi, Chim. Anal. [Bucureşti]2, 52 (1972).Google Scholar
  15. 15.
    P. J. Krausz undJ. Kovacs, Ann. Univ. Sci. Budapest Sect. Chim.4, 37 (1962).Google Scholar
  16. 16.
    G. Boda, Cs. Várhelyi undA. Mostis, Stud. Univ. Babeş-Bolyai10, 63 (1965).Google Scholar
  17. 17.
    I. Gănescu, A. Popescu undM. Proteasa, Coll. Czechoslov. Chem. Commun.36, 3088 (1971).CrossRefGoogle Scholar
  18. 18.
    G. Brauer, Handbuch der präparativen anorganischen Chemie, 2. Bd., 2. Aufl., S. 1334. Stuttgart: Enke. 1962.Google Scholar
  19. 19.
    A. Werner, Ann. Chem.386, 1 (1912).CrossRefGoogle Scholar
  20. 20.
    Cs. Várhelyi undS. Kövendi, J. prakt. Chem.34, 209 (1966).CrossRefGoogle Scholar
  21. 21.
    M. Chamberlain undC. J. Bailar, J. Amer. Chem.81, 6412 (1959).CrossRefGoogle Scholar
  22. 22.
    F. Fujita, K. Nakamoto undM. Kobayashi, J. Amer. Chem. Soc.78, 3295 (1956).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag 1975

Authors and Affiliations

  • Ion Gănescu
    • 1
    • 2
  • Csaba Várhelyi
    • 1
    • 2
  • Gheorghe Brînzan
    • 1
    • 2
  • Liviu Boboc
    • 1
    • 2
  1. 1.Facultatea de StiinţeLehrstuhl für Anorganische Chemie der Universität CraiovaCraiovaRumänien
  2. 2.Babeş-Bolyai UniversitätClujRumänien

Personalised recommendations