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Alkylation of phenols with mixed-functional compounds

2. Alkenylation of o- and p-cresols with allyl alcohol
  • N. I. Shuikin
  • E. A. Viktorova
  • I. E. Pokrovskaya
  • T. G. Malysheva
Article
  • 29 Downloads

Summary

  1. 1.

    The alkenylation of o- and p-cresols with allyl alcohol in the presence of acid catalysts was studied.

     
  2. 2.

    The reaction occurs by two paths: C- and O-allylation.

     
  3. 3.

    Isomeric allyl cresols, their cyclization products-the corresponding coumarans-and allyltolyl ethers are the allylation products.

     
  4. 4.

    The formation of an allylation product of cresols with the double bond of allyl alcohol-2-(3-methyl-6-hydroxyphenyl)propanol-1-was observed for the first time.

     

Keywords

Alcohol Ether Phenol Double Bond Alkylation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau 1962

Authors and Affiliations

  • N. I. Shuikin
    • 1
  • E. A. Viktorova
    • 1
  • I. E. Pokrovskaya
    • 1
  • T. G. Malysheva
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityUSSR

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