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β-Dicarbonyl compounds

Communication 10. The difference in chemical behavior between aliphatic and cyclic β-dicarbonyl compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

Cases of the different chemical behavior of aliphatic and cyclic β-dicarbonyl compounds have been considered. The following properties are characteristic for β -diketones of the type of dihydroresorcinol: hindered Michael and C-alkylation reactions, tendency to form alkylidene-bis-β-diketones by the action of aldehydes, incapability of undergoing the Mannich reaction, inertness of the halogen atom of enolized 2-bromo derivatives, and the brominatioh of the enol ethers by N-bromosuccinimide in the second position.

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Authors and Affiliations

  1. The N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    S. I. Zav'yalov & L. P. Vinogradova

Authors
  1. S. I. Zav'yalov
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  2. L. P. Vinogradova
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Zav'yalov, S.I., Vinogradova, L.P. β-Dicarbonyl compounds. Russ Chem Bull 10, 1529–1533 (1961). https://doi.org/10.1007/BF00906146

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  • DOI: https://doi.org/10.1007/BF00906146

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