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Synthesis of liquid 1, n-hexamethylpoly (phenylethyl) methylsiloxanes and investigation of their properties

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The lower members of the homologous-polymer series of 1, n-hexamethylpoly(phenylethyl)methylsiloxanes were synthesized and their viscous properties studied.

  2. 2.

    When a hydrogen atom in the aromatic nucleus is replaced by a methyl group or chlorine atom, the activation energy of viscous flow increases, in correspondence with the increase in the polarity of the organic radicals, in the order C6H5- < CH3C6H4- < ClC6H4-.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    K. A. Andrianov, A. A. Zhdanov & V. A. Odinets

Authors
  1. K. A. Andrianov
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  2. A. A. Zhdanov
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  3. V. A. Odinets
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Andrianov, K.A., Zhdanov, A.A. & Odinets, V.A. Synthesis of liquid 1, n-hexamethylpoly (phenylethyl) methylsiloxanes and investigation of their properties. Russ Chem Bull 10, 1507–1514 (1961). https://doi.org/10.1007/BF00906142

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  • DOI: https://doi.org/10.1007/BF00906142

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