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Disproportionation reactions of organic compounds containing zirconium, titanium, and iron

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study has been made of the action of water on zirconium triacetylacetonate chloride, zirconium tribenzoylacetonate nitrate, zirconium isopropoxytriacetylacetonate, and the chlorides iron diacetyl- and dibenzoylacetonate. In all cases a disproportionation reaction took place, leading to the formation of zirconium tetraacetylacetonates or tetrabenzoylacetonates, or of iron triacetylacetonates or tribenzoylacetonates.

  2. 2.

    By the interaction of ethyl orthotitanate and acetic anhydride, taken in 1∶2 mole ratio, there was obtained crystalline tetraacetoxytetraethoxytrititanoxane (CH3CO2)4(C2H5O)4 Ti3O2.

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Authors and Affiliations

  1. Kazan' Institute of Organic Chemistry, USSR Academy of Sciences, USSR

    É. M. Brainina & R. Kh. Freidlina

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  1. É. M. Brainina
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  2. R. Kh. Freidlina
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Brainina, É.M., Freidlina, R.K. Disproportionation reactions of organic compounds containing zirconium, titanium, and iron. Russ Chem Bull 10, 1489–1492 (1961). https://doi.org/10.1007/BF00906138

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  • DOI: https://doi.org/10.1007/BF00906138

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